In scenarios such as 42 MPa hydrogen cracking, 70 MPa ultra-high pressure gas transportation, and 100 MPa water jet cutting, once the system exceeds pressure, the reactor, separation tower, or pipeline will be torn apart within milliseconds. China's high-pressure relief valves (PSV/PRV) serve as the last active pressure relief barrier. Their pressure tolerance accuracy, material compatibility, and compliance with regulations directly determine the life of the equipment, the safety of personnel, and environmental compliance. This article focuses on China's high-pressure relief valves and presents a one-stop solution for selection, material selection, and safety regulations.